Abstract

Diffusion of carbon atoms (ions) in an iron matrix based on crystallography is considered. Structures are determined for a chemisorbed carbon layer and its concentration. The carbon diffusion coefficient in γ-Fe during electrocontact compaction is calculated. The elementary act of C+n movement into neighboring iron octahedral interstices is considered as a basic homogenization mechanism. Intensification of C diffusion in γ-Fe is explained by the effect of an external electric field on the degree of carbon atom ionization in the iron crystal lattice interstices.

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