Abstract
Crystallization in an undercooled Aluminum (Al) droplet occurs via the formation of crystalline nuclei by homogeneous or heterogeneous nucleation and successive growth of nuclei. Clusters of a new phase appear in the system due to fluctuations and after reaching a critical size grow up to microscopic size. Crystallization event at low undercooling 6.4°C of 9.91 mg in compact Al sample was detected using isothermal differential scanning calorimetry (DSC) after several tenths of minutes. In this case, standard analysis based on Johnson-Mehl-Avrami-Kolmogorov (JMAK) model is not appropriate as Avrami parameter n obtained by fitting of DSC data is too low (n ≤ 1 and thus the dimensionality of the system d = n – 1 ≤ 0). Al growth rate is extremely high and that is why we presume that the time delay of crystallization, detected by DSC, is slightly higher than nucleation time delay. A homogeneous nucleation model is applied to determine the basic characteristics of nucleation: the size distribution of nuclei, nucleation rate, total number of nuclei and crystallization fraction at the nucleation process. The number of atoms in a liquid Aluminum droplet decreases with time as the formation of a new crystalline phase occurs. As a consequence, a decrease in stationary nucleation occurs. It is shown that decrease in the number of atoms in a liquid Al droplet is predominantly caused by formation of subcritical clusters.
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