Abstract
The mayenite glass with a wide high-temperature stability ([Formula: see text]C) was innovatively synthesized by the aerodynamic levitation (ADL) containerless technique without conventional glass-forming addictives. The crystallization mechanism and kinetics of mayenite glass were studied by X-ray diffraction (XRD), scaning electron microscopy (SEM), Raman spectra and differential scanning calorimetry (DSC) analysis. The crystallization mechanism study revealed that structure and morphology mainly evolved near the crystallization peak temperature by the networking process of isolated AlO4 tetrahedra units, resulting in the growth mechanism changing from “two-dimensional” to “three-dimensional”. Crystallization kinetics calculations based on the non-isothermal Matusita model indicated that the activation energy for the crystallization of mayenite glass was 844[Formula: see text]kJ[Formula: see text]mol[Formula: see text]. The calculated growth morphology parameters (m and n) also confirmed the surface crystallization along with bulk crystallization mechanism for the mayenite glass. This present study supplied a thermal–physical understanding about the crystallization of mayenite glass, which could be further applied in the exploitation of glass/glass–ceramics in the CaO–Al2O3 binary system.
Published Version
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