Crystallization kinetics and structural development of Bi2GeO5 glass-ceramics fabricated by the modified incorporation technique

Abstract

This study focuses on the fabrication and crystallization kinetics of bismuth germanate (Bi2GeO5) crystals in glass ceramics. Bismuth germanate glass-ceramics were produced from a base glass containing 58.4 mol% Bi2O3, 23.4 mol% GeO2, and 18.2 mol% B2O3 using a modified incorporation technique. Differential thermal analysis was used to determine the crystallization temperature. The X-ray diffraction results showed a dominant peak corresponding to the pure Bi2GeO5 phase, which has an orthorhombic crystal structure. The local Avrami exponent (n(x)) and local crystallization activation energy (Ec(x)) were determined using a non-isothermal method with heating rates ranging from 5 to 20 °C/min. The results indicated that the crystal growth process of the glass-ceramics occurred in all three dimensions, with Avrami exponent values ranging from 1.79 to 2.5. The microstructure also revealed uniform crystallization across the surface and bulk diffusion of crystallites. The modified incorporation method successfully enhanced the crystallization of Bi2GeO5 glass-ceramics, resulting in the transition from one-dimensional needle-like crystals to the desired crystal dimensions.