Abstract

The effects of various polymeric additives on the crystallization of CaCO 3 in simple soda-based detergent formulations were investigated. The adherence of CaCO 3 on cotton, a great disadvantage of soda-based detergents, was significantly diminished by copolymers of polystyrene sulfonates. A mechanism in which these additives promote the nucleation of CaCO 3 is proposed. Polyacrylates cause an increasing adherence of CaCO 3 on cotton, because the chains adsorb on cotton and CaCO 3

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