Abstract
The effect of molecular cross-linking on the crystallization of random ethylene–1-butene copolymers obtained from hydrogenation of model polybutadiene was studied by means of differential scanning calorimetry. The copolymers were modified with different concentrations of organic peroxide in the molten state to generate different crosslink levels. Under isothermal conditions, the crystallization rate of the modified polymers decreased with the average molecular weight likewise to that observed in the unmodified copolymers. Original and modified polymers show similar isothermal crystallization rates when compared to equivalent weight average molecular weights. Under no isothermal crystallization conditions, the temperature and the enthalpy of crystallization of the modified polymer decreased almost linearly with the concentration of peroxide. The activation energy for crystallization increased with the concentration of peroxide indicating that the increment in molecular crosslinking restricts the crystallization process.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
