Abstract
Chemical preparation, X-ray single crystal, thermal analysis, IR and Raman spectroscopic investigations of (C8H22N2)(AsO2(OH)2)2 are described. The 2-(diisopropyl ammonium)ethylammonium-bis-(dihydrogen arsenate) crystallizes in the orthorhombic system with P212121 space group. The unit cell dimensions are a = 8.3009(2) A, b = 8.5640(3) A, c = 23.1480(7) A with V = 1645.57(9) A3 and Z = 4. The structure was solved using direct method and refined to a reliability R factor of 4.37 %. The (C8H22N2)(AsO2(OH)2)2 structure provides a new interesting example of infinite inorganic layers of [H2AsO4] n n− where the arsenate groups are interconnected by O–H···O hydrogen bonds. The crystal structure can be described as infinite layers centered by planes (110). Thermal analysis reveals the anhydrous character of the compound. IR and Raman spectra are reported and discussed on the basis of group theoretical analysis.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Inorganic and Organometallic Polymers and Materials
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
