Crystal structure of ZnO nanocrystals synthesized by the spray pyrolysis method

Abstract

The paper discusses the issues related to the influence of technological conditions of synthesis by ultrasonic spray pyrolysis on the size and lattice parameters of ZnO:Mn nanocrystals. It is found that, depending on the concentration of zinc nitrate in the base solution from 5% to 10%, the synthesized nanocrystals have sizes ranging from 36÷40 nm for small solution droplets and 51÷55 nm for large droplets, respectively. Based on the X-ray diffraction data, it is found that the nanocrystals of small sizes have a more perfect crystal structure with a small number of intrinsic defects compared to the nanocrystals of larger sizes.