Crystal structure of a mixed-ligand terbium(III) coordination polymer containing oxalate and formate ligands, having a three-dimensional fcu topology.

Abstract

The title compound, poly[(μ 3-formato)(μ 4-oxalato)terbium(III)], [Tb(CHO2)(C2O4)] n , is a three-dimensional coordination polymer, and is isotypic with the La(III), Ce(III) and Sm(III) analogues. The asymmetric unit contains one Tb(III) ion, one formate anion (CHO2 (-)) and half of an oxalate anion (C2O4 (2-)), the latter being completed by application of inversion symmetry. The Tb(III) ion is nine-coordinated in a distorted tricapped trigonal-prismatic manner by two chelating carboxyl-ate groups from two C2O4 (2-) ligands, two carboxyl-ate oxygen atoms from another two C2O4 (2-) ligands and three oxygen atoms from three CHO2 (-) ligands, with the Tb-O bond lengths and the O-Tb-O bond angles ranging from 2.4165 (19) to 2.478 (3) Å and 64.53 (6) to 144.49 (4)°, respectively. The CHO2 (-) and C2O4 (2-) anions adopt μ 3-bridging and μ 4-chelating-bridging coordination modes, respectively, linking adjacent Tb(III) ions into a three-dimensional 12-connected fcu topology with point symbol (3(24).4(36).5(6)). The title compound exhibits thermal stability up to 623 K, and also displays strong green photoluminescence in the solid state at room temperature.