Abstract
The title compound, [Cu(C20H23N3O4)], crystallizes in the space group Cc with two independent molecules in the asymmetric unit. The CuII atoms are each coordinated by the pentadentate Schiff base ligand in a distorted trigonal bipyramidal N3O2 geometry. The equatorial plane is formed by the two phenolic O atoms and the amine N atom, while the axial positions are occupied by the two imine N atoms. In the crystal, the two independent molecules are each connected into a column along the b axis through intermolecular O—H⋯O hydrogen bonds. The two independent columns are further linked through an N—H⋯O hydrogen bond, forming a double-column structure.
Highlights
The title compound, [Cu(C20H23N3O4)], crystallizes in the space group Cc with two independent molecules in the asymmetric unit
The CuII atoms are each coordinated by the pentadentate Schiff base ligand in a distorted trigonal bipyramidal N3O2 geometry
The equatorial plane is formed by the two phenolic O atoms and the amine N atom, while the axial positions are occupied by the two imine N atoms
Summary
The title compound, [Cu(C20H23N3O4)], crystallizes in the space group Cc with two independent molecules in the asymmetric unit. The CuII atoms are each coordinated by the pentadentate Schiff base ligand in a distorted trigonal bipyramidal N3O2 geometry. The two independent molecules are each connected into a column along the b axis through intermolecular O—
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