Abstract
In the title compound, C24H22Br2N2S, the dihedral angles between the central pyrimidine ring and the pendant bromobenzene rings are 11.02 (11) and 13.20 (12)°. The butyl side chain adopts a gauche conformation [C—C—C—C = −67.4 (4)°]. In the crystal, weak aromatic π–π stacking is observed between the pyrimidine ring and one of the benzene rings [centroid–centroid separation = 3.6718 (17) Å].
Highlights
C24H22Br2N2S, the dihedral angles between the central pyrimidine ring and the pendant bromobenzene rings are 11.02 (11) and 13.20 (12)
Weak aromatic – stacking is observed between the pyrimidine ring and one of the benzene rings [centroid–centroid separation = 3.6718 (17) A ]
Supporting information for this paper is available from the IUCr electronic archives (Reference: HB7313)
Summary
C24H22Br2N2S Mr = 530.32 Monoclinic, P21=c a = 9.5636 (19) Ab = 10.630 (2) Ac = 23.708 (6) A = 112.82 (3). C24H22Br2N2S, the dihedral angles between the central pyrimidine ring and the pendant bromobenzene rings are 11.02 (11) and 13.20 (12). The butyl side chain adopts a gauche conformation [C—C—C—C = À67.4 (4)]. Weak aromatic – stacking is observed between the pyrimidine ring and one of the benzene rings [centroid–centroid separation = 3.6718 (17) A ]
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