Crystal structure and properties of the new complex vanadium oxide K 2SrV 3O 9

Abstract

The new complex vanadium oxide K 2SrV 3O 9 has been synthesized and investigated by means of X-ray powder diffraction (XPD), electron microscopy and magnetic susceptibility measurements. The oxide has an orthorhombic unit cell with lattice parameters a = 10.1922(2) Å, b = 5.4171(1) Å, c = 16.1425(3) Å, space group Pnma and Z = 4. The crystal structure of K 2SrV 3O 9 has been refined by Rietveld method using X-ray powder diffraction data. The structure contains infinite chains built by V 4+O 5 square pyramids linked to each other via VO 4 tetrahedra. The chains form layers and potassium and strontium cations orderly occupy structural interstices between these layers. Electron diffraction as well as high resolution electron microscopy confirmed the structure solution. Magnetic susceptibility measurements revealed an antiferromagnetic interaction with J of the order of 100 K inside the chains and no long-range magnetic order above 2 K. The origin of the magnetic exchange is likely a result of super-exchange interaction through the two VO 4 tetrahedra linking the polyhedra with the magnetic V 4+ cations.