Abstract
A new metal-organic polymer [Fe(pydc)(H2O)] (1; H2pydc = pyridine-2,5-dicarboxylic acid), has been hydrothermally synthesised and characterised by X-ray diffraction, showing that 1 is a three-dimensional framework featuring two-dimensional carboxylate-bridged layers based on canted dimeric iron(II) subunits. Magnetic measurements demonstrate that, although the carboxylate and pyridyl bridges are present in the layer, 1 exhibits only a weak antiferromagnetism.
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