Abstract
Abstract The crystal structure of the GdMSi compounds (M first-row transition metal) was divided into two types: the tetragonal PbFCl-type structure for M Mn , Fe , Co and the hexagonal AlB 2 -type structure for M Ti , Cu , Zn . Examination of crystallographic data and the results of the electrical and magnetic measurements suggested that the change in the crystal structure of GdMSi depends on the atomic radii of the first-row transition metals and the concentration of the conduction electrons in the conduction bands of the compounds.
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