Abstract
The structure of a mixed-ion Ba2+–K+β-ferrite, Ba0.39K0.39Fe11O17.03, has been determined by X-ray diffraction, and refined in the hexagonal space-group P63/mmc, R(F)= 3.4%, Rw(F2)= 5.9%. At least two possible charge compensation mechanisms could be identified: (i) a Frenkel defect of Fe3+ ions indicating an extra oxygen ion in the conduction plane, and (ii) Fee+ ions and/or vacancies at Fe3+ ion sites in the spinel block. The K+ ions and most of the Ba2+ ions in the conduction plane are found at a 6(h) site near the 2(d)(Beevers-Ross) site; the remainder of the Ba2+ ions are at a 6(h) site at x≈ O.88, y=–x.
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