Abstract
One new supramolecular structure organic-inorganic hybrid compound (3-C6H8N)4(PMo12O40)·H2O constructed by phosphomolybdate and 3-methylpyridine via hydrogen bond and π-π stacking interactions was obtained by hydrothermal reaction and characterized by IR, UV-vis, TG-DTA, FL, CV, and single-crystal X-ray diffraction. The luminescent properties of the compound at room temperature were investigated. The title compound exhibits good thermal stability and blue fluorescence in the aqueous solution at room temperature. The CV curve revealed a pair of irreversible redox wave and two pairs of redox wave, which are one-electron and two-electron quasireversible redox processes of Mo. Supplemental materials are available for this article. Go to the publisher's online edition of Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry to view the supplemental file.
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