Abstract

Pentagonal nanorods (PNRs) and nanoparticles (PNPs) covered by mismatched shell layers are theoretically investigated. Mechanical stresses and elastic energies of such objects are calculated analytically and analyzed in the framework of linear isotropic elasticity. Difference between elastic modules of core and shell is taken into account. The threshold radiuses as the minimal radiuses of PNR and PNP for which the formation of the shell layer is energetically favorable are found. The threshold radius is approximately 10 nm for PNPs and 100 nm for PNRs of typical face-centered cubic (FCC) metals. The optimal magnitudes of mismatch parameter giving the maximal energy release for shelled PNRs and PNPs are determined.

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