Abstract
The title compound crystallizes in the monoclinic space groupP21/n,a=13.429(3),b=18.248(6),c=14.497(4)A,β=90.61(2)°,Z=8, with two independent molecules in the asymmetric unit. The structure was solved by heavy-atom methods, and refined to a finalR value of 0.040. The phosphoranium ring adopts a chair conformation which is substantially flattened at the phosphorus end. The ring conformation and torsion angles are compared with similar compounds.
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