Abstract
Dicyclohexylammonium 2-mercaptobenzoatotriphenylstannate crystallizes in the monoclinicP21/n space group (a=11.171(2),b=17.891(5),c=17.190(3)A;β=105.08(2)°). The asymmetric unit consists of a [(cyclo-C6H11)2NH2]+ cation hydrogen bonded (N⋯O1=2.803(4) A) to the stannate anion; the [(C6H5)3Sn]+ group is covalently linked to the sulfur end (Sn-S=2.427(1)A) of the [SC6H4C(O2)O1]−2 moiety. The tin is five-coordinate in a distortedcis-trigonal bipyramidal environment in which the carboxyl O2 atom (Sn-O2=2.704(3)A) and theipso-carbon of a phenyl ring occupy apical positions (O2-Sn-C1=168.7(1)°); the Sn-Caxial bond (Sn-C1=2.179(3)A) is longer than the Sn-Cequatorial bonds (2.136(4), 2.139(3)A). The stannate anion is linked to an adjacent cation (N′⋯O1=2.880(4)A) to form a tightly held three-dimensional network structure.
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