Abstract

The chapter considers the technology of the crude distillation unit in general. The crude distillation unit is at the front-end of the oil refinery. The desalting process and distillation of crude oil are included in the crude distillation unit (CDU). The desalting process of crude oil is imperative to ensure the good quality of crude oil, that is, to remove impurities before its transfer to refining. This procedure minimizes or eliminates harmful substances such as sulfur, water, salts, and even mechanical impurities, which ensures a long operation of pipelines. However, the desalting process is only part of the distillation unit. The other phase of this unit is as already mentioned above is: distillation. Distillation is a more physical than a chemical process. The distillation process is characterised by mass-thermal transfer of materials, which leads to the obtaining of fractions. The distillation in the crude distillation unit is carried out consecutively in two ways: atmospheric and vacuum. In the Russian Federation, we classify oil refining plants in general as follows: fuel, fuel-oil, fuel-petrochemical, and fuel-oil-petrochemical. Also, regardless of the profile of the refinery, great importance is given to the crude distillation unit. The crude distillation unit, if well modeled and organized, makes it possible to obtain already more light products at this stage; therefore, there is a reduction of heavy residues, the refinement of which requires more expensive processes such as hydrocracking or catalytic cracking. The oil topping column K-1, within this framework, has been adopted in several oil refining plants in addition to the main column commonly referred to as K-2. The principal purpose of column K-1 is the separation of light gasoline and the major part of dissolved gases from crude oil. This first step of distillation at K-1 has the effect of normalizing the amount of gasoline hydrocarbons and stabilizing the operation of the main column K-2 despite possible fluctuations in the composition of crude oil. Besides, the CDU equipped with column K-1 demonstrates an increase in some valuable products such as methane, ethane, naphtha, etc.

Highlights

  • Many crude oils usually contain besides the basic elements of its chemical composition hydrocarbons such as sulfur, oxygen, nitrogen, and mechanical impurities [1]

  • For a better understanding of classificatory at the quality, the Petroleum world has adopted a benchmark called stallion as Brent Blend produced in the North Sea, West Texas Intermediate (WTI) from the USA, Dubai Crude from Dubai

  • The degree of pre-treatment of oil for transportation does not consider the content of chloride salts and the content of organochlorine compounds [8], literally because all salts are large in water and not in oil [9], in connection with the decision of the Russian Federation to join the world trade organization (WTO), the requirements for oil are unified following the requirements for prepared oil according to ASTM D1250-97 [4] and EN 224 [3]

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Summary

Introduction

The distillation is heating a liquid solution or mixture of liquid stream to produce steam, and collecting and condensing that steam. The products of the distillation process are limited to the upper distillate and the bottom, the composition of which differs from the feed. The major purpose of distillation is the separation or splitting into two or more products from a feed [32]. One of the components of crude oil refining is distillation, a stage of refining. The fractionation or distillation column exists in practically all oil refining technologies through reforming, thermal cracking, hydrocracking, etc. Before receiving the petroleum products common to users, the oil goes through several stages before becoming a finished product. Some of these stages are [1, 9, 20, 21]:. Treatment of petroleum products (hydrotreatment, desulphurization, etc.)

Pre-treatment of crude oil
Oil emulsion
The demulsifier (surfactant)
Mechanisms and devices of process of dehydration-desalination (pre-treatment) of oil crude
The salts in crude oil
Description of dewatering of oil emulsions with electrostatic desalter
Description of electrostatic desalter and its process
Desalting processes at a refinery
Example of modeling of electrostatic desalter at refinery
Materials balances of electrostatic desalter
Methods
Modeling of the desalting process with electrostatic desalter
Mechanical modeling of electrostatic desalter (theory)
Resolution example based on our electrostatic desalter
Summary
Description and characteristics crude distillation unit (CDU)
Description of the distillation column and its operation
The plates for distillation columns of oil plants
The lattice or grid plates
The cap plates
The valve plates
The jet plates
Determination of the yield (material balance) of the furnace
Examples of material balance of atmospheric distillation unit (ADU)
Crude distillation unit (CDU) used in Russia compared to the typical model
Conclusion
Findings
56. ISBN: 5-29203605-06
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