Abstract

In the present work, using the principle of isomorphism and complete scaling method, a new scaled crossover parametric equation of state and a new representation for the refractive index of binary systems has been introduced. We have introduced a stepwise algorithm for calculating the mixing parameters defining scaling fields in terms of physical fields. Comparing the experimental data for five thermophysical properties and for eight binary liquid systems, it has been observed that this new approach is able to predict all thermophysical properties quite well.

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