Abstract

Ion yields upon the cascade decays of single vacancies in K to O shells of an isolated iodine atom are calculated by the method of construction and analysis of the cascade decay trees. Branching ratios needed for the simulations are calculated based on Pauli–Fock partial transition widths. Partial photoionization cross sections are calculated with accounting for the core relaxation effect and used to calculate the cross sections of I q+ photoions production in the 0.01–100 keV incident photon energy range. Accounting for the spin–orbit splitting and the splitting due to electron–electron interaction is shown to be important when calculating mean energies and probabilities of the transitions between energetically closely lying ionic configurations. On the other hand, inclusion of the additional shake-off electron ejections, in spite of complicating severely the decay trees, is found to affect little calculated cascade ions production probabilities.

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