Cross sections for electron impact excitation of the vibrationally resolved AΠ1 electronic state of carbon monoxide

Abstract

The authors report new differential cross section measurements for electron impact excitation of the A (1)Pi(v(')) states of carbon monoxide. The energy range is 20-200 eV. They also reanalyze the A (1)Pi(v(')) manifold cross sections of Middleton et al. [J. Phys. B 26, 1743 (1993)] in order to provide a basis for comparison with our new vibrationally resolved differential cross sections. Excellent agreement is found between the two sets of measurements at all common energies. From 20 to 200 eV the present differential cross sections are extrapolated and integrated, and the corresponding integral excitation cross sections determined. New scaled Born integral cross sections, calculated as a part of the present study, are compared against these experimental integral cross sections, with excellent agreement being found for all the A (1)Pi(v(')=0-7)<--X (1)Sigma(g) (+)(v(")=0) transitions. In addition our scaled Born integral cross sections are found to be in excellent agreement between 300 and 1500 eV with those derived from the previous experiments of Lassettre and Skerbele [J. Chem. Phys. 54, 1597 (1971)] and of Zhong et al. [Phys. Rev. A 55, 1799 (1997)] and from near threshold to 15 eV with those derived from Zobel et al. [J. Phys. B 29, 813 (1996)] and Zetner et al. (J. Phys. B 31, 2395 (1998)].