Cross-Polarization from the Dipolar Reservoir under the Mismatched Hartmann–Hahn Condition

Abstract

Cross-polarization from the dipolar reservoir for a range of mismatched Hartmann–Hahn conditions has been considered. Experiment, in general, agrees with the dispersive Lorentzian behavior expected on the basis of quasi-equilibrium theory. It is observed that inclusion of additional mechanisms of polarization transfer lead to an improvment of the fit of the experimental results. The utility of extending the technique to the case of ordered long chain molecules, such as liquid crystals, for the measurement of the local dipolar field is also presented.