Abstract
The improved catalytic conversion of bioresources, namely unsaturated fatty acid derivatives, is presented. The targeted reaction is ruthenium-catalyzed cross-metathesis with functionalized olefins (α,β-unsaturated esters), that affords shorter diesters. These can be used as biosourced (pre)monomers for the production of polyesters. It is demonstrated that switch from terminal to internal cross-metathesis partners (that is, from methyl acrylate to methyl crotonate) allows use of ppm-level catalyst loadings, while retaining high productivity and selectivity. This was exemplified on a commercial biosourced fatty acid methyl esters mixture, using minimal purification of the substrate, on a 50 g scale. We propose that this improved catalytic behavior is due to the sole presence of more stable alkylidene intermediates, as the notoriously unstable ruthenium methylidene species are not formed using an internal functionalized olefin.
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