Cross-interaction of volatiles in fast co-pyrolysis of waste tyre and corn stover via TG-FTIR and rapid infrared heating techniques

Abstract

Using fast infrared heating technology to minimize the pyrolysis temperature differential and optimizing secondary reactions is advantageous for studying co-pyrolysis behaviors. In this study, the co-pyrolysis behaviors of waste tyres (WT) and corn stover (CS), including product distribution, pyrolysis kinetics, and thermodynamics, were studied using TGA-FTIR analysis and fast infrared heating reactor. The DTG curves for the co-pyrolysis of WT and CS significantly differed from the calculated values, implying that the pyrolysis intermediates produced by CS during the pyrolysis process may have synergetic effects with the pyrolysis of WT. The apparent activation energies using the Kissinger-Akahira-Sunose (KAS) and Flynn-Wall-Ozawa (FWO) methods were similar, 244.88 kJ/mol and 245.93 kJ/mol, respectively. The experiment results suggest that the bio-oil yield increased first and then decreased with a further temperature increase. The yield of bio-oil gradually increased from 35.36% to 46.06% as temperature rose from 500 °C to 700 °C; but the further increasing to 800 °C decreased the bio-oil yield to 40.72%. The aromatic compounds in tar gradually increased with increasing the temperature, while the aliphatic compounds increased initially and then reduced. Meanwhile, the oxygenated compounds first decreased and then increased with increasing the pyrolysis temperature. The yield of light oil components (C＜10) increased from 5.11% at 400 °C to 7.71% at 700 °C. A further increase in the pyrolysis temperature to 800 °C reduced the light oil content to 4.93%.