Critical pitting temperature for Type 254 SMO stainless steel in chloride solutions

Abstract

The variation with time of the open circuit potential of high molybdenum containing stainless steel (Type 254 SMO) was measured in 4% sodium chloride solution in the temperatures range 30–100 °C. The plot of steady state potentials as function of temperature showed an inflection at 50 °C, attributed to the decrease of oxygen solubility in test solution above 50 °C. Potentiodynamic cycling anodic polarization technique was used to determine the critical pitting potential ( E pit) and the critical protection potential ( E prot) of the steel in 4–30% NaCl solutions at temperatures between 30 and 100 °C. By plotting the two values versus solution temperature, the corresponding critical pitting (CPT) and the critical protection (CPrT) temperatures were determined. Both parameters decreased with increasing chloride content. Above the CPT, E pit and E prot decreased linearly with log[Cl −]. The addition of bromide ions to the solution shifted both E pit and E prot towards positive values. In 4% NaCl, E pit increased linearly with pH in the range 1–10. The combined effect of chloride ion concentration and pH on the morphology of the pits was examined by scanning electron microscopy (SEM) following potentiodynamic cycling anodic polarization.