Abstract

The growing demand for critical raw materials (rare earth elements—REE, Nb, Ta, and others) enforces a need to look for their alternative sources. Distortions of the mineral supply chain caused by COVID-19 have necessitated a re-evaluation of what exists as mining waste from previous exploitation. Consequently, this study aims to provide an inventory of raw materials on the Indonesian Tin Islands (Bangka and Belitung). Geological and mineralogical examinations on Bangka have permitted an economic appraisal of tailings from the processing of cassiterite-bearing sands and confirmed the presence of REE-bearing minerals, chiefly monazite and xenotime, zircon, ilmenite, rutile, niobium-tantalum phases. In general, the mineral content of the tailings varies depending on the sampling site and the type of processing used during ore-production. ICP-MS (inductively coupled plasma–mass spectrometers) analyses revealed anomalous concentrations of LREE (light rare earth elements): La > 5%, Ce > 5%, Pr > 1%, Nd > 1%, Sm > 1% and HREE+Y (heavy rare earth elements and yttrium) up to 2.51 wt%. High values have been found for the “most critical” metals of the HREE group: Dy (up to 0.34 wt%), Tb (up to 0.08 wt%), Eu (up to 61.8 ppm), Nd (>1.0 wt%), and Y (up to 1.20 wt%). In addition, the following contents have been defined: Ga (to 0.03 wt%); Hf (to 0.64 wt%); Ta (to 0.08 wt%); Nb (to 0.23 wt%); W (to 0.14 wt%); Zr (>5.0 wt%); and Sc (to 0.01 wt%). Such high concentrations suggest the tailing dumps to be a potential new source of “critical raw materials”.

Highlights

  • Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations

  • Mining operations connected with exploitation and processing of mineral raw materials are responsible for the generation of waste material stored on dumping sites and in post-flotation settling ponds [32]

  • Distortion of the supply chain of mineral resources caused by the COVID-19 pandemia created an urgent need to look for alternative sources of key raw materials

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Summary

Introduction

Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. In the global modern economy, metals used in high technology and advanced industry play an increasingly important role [1,2,3]. They are referred to as critical, strategic, or pivotal metals [4]. Countries where these are in demand strive to gain access to the necessary amounts of high-quality resources ensuring their mineral security [3]

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