Abstract

AbstractThe Hamiltonian for a completely degenerate d‐band including intra‐atomic Coulomb and exchange interactions is derived and studied using the alloy analogy method. Green's function, the magnetic susceptibility and a criterion for the appearance of ferromagnetism are obtained by this method. The dependence of the magnetization on the exchange constant and on the number of electrons per atom is calculated for strong Coulomb correlation and for the uncorrelated case. It is shown that Coulomb correlation of any strength leads to a decrease of the exchange interaction constant needed to produce ferromagnetism and additionally to a change in the shapes of the magnetic dependences for (and only for) weakly ferromagnetic metals.

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