Abstract

Palladium-catalyzed annulation of acyl fluorides is depicted in the cover image. Acyl fluorides are converted into the corresponding polycyclic ketones in the presence of norbornene. The reaction proceeds via C−F and ortho C−H bond cleavage of acyl fluorides and the rearrangement of the carbonyl moiety by decarbonylation and CO reinsertion. More information can be found in the Full Paper by Y. Sakurai, Y. Ogiwara, and N. Sakai on page 12972.

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