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https://doi.org/10.1039/c7cc02859h
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Cite Publication Date: Jan 1, 2017 | |
 Citations: 14 |
Affiliation: University of Turin, National Research Council, University of Bologna
We describe the active template effect of a calix[6]arene host towards the alkylation of a complexed pyridylpyridinium guest. The acceleration of the reaction within the cavity is significant and rim-selective, enabling the efficient preparation of rotaxanes with full control of the mutual orientation of their nonsymmetric components.
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