Cost-effective microwave-assisted hydrothermal rapid synthesis of analcime-activated carbon composite from coal gangue used for Pb2+ adsorption.

Abstract

Heavy metal contamination of water has brought about serious harm to the ecological environment and also threatens human health to a certain extent. In this study, a composite structure comprised of analcime-activated carbon (ANA-AC) was synthesized in situ via a microwave-assisted hydrothermal method using coal gangue (CG) for the potential treatment of Pb2+ from aqueous solution. The products were systematically characterized using XRD, SEM, BET, FTIR, and XPS. The results showed that activated carbon was successfully integrated with the structure of the analcime and the BET surface area of the ANA-AC (20.82 m2/g) was much greater than that of the CG (9.33 m2/g) and ANA (10.04 m2/g) independently. The relationship between Pb2+ adsorption capacity and the initial solution concentration, adsorbent dosages, contact time, pH, and temperature was studied. Under optimal conditions (Pb2+ = 100mg/L, dosage = 0.1g, contact time = 6h, pH = 5.4-6, temperature = 298K), the maximum adsorption capacity of ANA-AC can reach 100%, which was higher than that of CG and ANA. The Langmuir isotherm model was in good agreement with the data obtained for Pb2+ adsorption, and the pseudo-second-order kinetic model was more suitable for describing the experimental data, showing that chemical adsorption was the controlling step during the adsorption process. In summary, analcime-activated carbon composite prepared from coal gangue could be used as an appropriate adsorbent for Pb2+ adsorption from an aqueous solution.