Abstract

A theoretical analysis of donor fluorescence intensity decay for a system of donor and trap (acceptor) end-labeled polymers has been developed to account for the effects of Forster nonradiative energy transfer (NRET) as a function of experimentally important parameters in a monodisperse polymer melt: polymer molecular weight, ratio of trap to donor concentration, and fraction of unlabeled polymer in the mix. The model distinguishes between donor- and trap-labeled material and employs intermolecular correlation functions which have been calculated to describe the chain statistics of a given polymer system

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