Abstract

Linear correlations between 13C NMR chemical shifts of unsubstituted terminal carbon atom of the allylic ligand in [(1-R-η3-C3H4)PdCl]2 and Na[(1-R-η3-C3H4)PdCl2] and the modified Hammett constants were established. Two-parameter correlations using the Swain-Lupton parameters R+, R−, and F were obtained.

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