Correlations between 13C NMR chemical shifts of [(1-R-η3-C3H4)PdCl]2 and Na[(1-R-η3-C3H4)PdCl2] and substituent constants

E M Evstigneeva,V R Flid

doi:10.1007/s11172-008-0150-4

Correlations between 13C NMR chemical shifts of [(1-R-η3-C3H4)PdCl]2 and Na[(1-R-η3-C3H4)PdCl2] and substituent constants

E M Evstigneeva, V R Flid

https://doi.org/10.1007/s11172-008-0150-4

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Journal: Russian Chemical Bulletin	Publication Date: Jun 1, 2008
Citations: 2

#Swain-Lupton Parameters #Two-parameter Correlations #Substituent Constants #Unsubstituted Carbon Atom #Unsubstituted Carbon #Atom Of Ligand #13C NMR Chemical Shifts #Terminal Carbon Atom #Hammett Constants #NMR Chemical Shifts

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Linear correlations between 13C NMR chemical shifts of unsubstituted terminal carbon atom of the allylic ligand in [(1-R-η3-C3H4)PdCl]2 and Na[(1-R-η3-C3H4)PdCl2] and the modified Hammett constants were established. Two-parameter correlations using the Swain-Lupton parameters R+, R−, and F were obtained.

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Correlations between 13C NMR chemical shifts of [(1-R-η3-C3H4)PdCl]2 and Na[(1-R-η3-C3H4)PdCl2] and substituent constants