Abstract

O and MeOD) were also determined to exa-mine isotope effects. Additional rate constants were measured to obtain thermodynamic parameters of activation such as enthalpies of activation and entropies of activation which are summarized in Table 2.As shown in Table 1, the first-order rate constants increase in the order TFE-water < acetone-water < ethanol-water < methanol-water. The rate constants also increase as the water content in the mixed solvents increases, indicating that the reaction rate is accelerated by the solvent with higher ionizing power

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