Abstract
AbstractStructural properties of normal‐type spinel ZnCr2Se4 have been studied as a function of temperature by means of neutron diffraction. It is found that the structural phase transition (TC) from a cubic to orthorhombic symmetry simultaneously occurs at the antiferromagnetic phase transition temperature (TN ∼ 21 K), where the cubic and orthorhombic symmetry is 7Oh‐Fd3m and 24D2h‐Fddd, respectively. The structural phase transition is mainly characterized by the cooperative displacements of Se2– ions, which are induced by a magnetostriction resulting from the magnetic interaction of Cr3+ ions in CrSe4 chains along [110]. The antiferromagnetic magnetic structure below TN is made by a spiral magnetic coupling between the ferromagnetic CrSe4 chains around crystallographic screw axes, which are parallel to an orthorhombic C axis. The spiral long‐range order of the spins of Cr3+ is incommensurate and its periodicity of q along a reciprocal lattice axis C* shows temperature dependence from about 0.47 (2.5 K) to 0.43 (18 K). The spiral periodicity of the spin order along the C axis shows a first order transition at about 21 K.
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