Abstract
HighlightsA strategy that combines multi-mode scanning probe microscopy-based electrical characterization and nano-infrared spectroscopy is developed.A series of samples with different coupling agents and nanoparticles are characterized to unveil the local structure-property correlation of the interface in ferroelectric polymer nanocomposites.The formation of hydrogen bond between the surface modifiers and the ferroelectric polymer enhances the β-phase content and reduces the domain size of the interface, and hence promotes the local piezoelectric effect and breakdown strength.
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