Abstract
BackgroundThe aim of the study was a statistical evaluation of the statistical relevance of potentially explanatory variables (atmospheric deposition, meteorology, geology, soil, topography, sampling, vegetation structure, land-use density, population density, potential emission sources) correlated with the content of 12 heavy metals and nitrogen in mosses collected from 400 sites across Germany in 2015. Beyond correlation analysis, regression analysis was performed using two methods: random forest regression and multiple linear regression in connection with commonality analysis.ResultsThe strongest predictor for the content of Cd, Cu, Ni, Pb, Zn and N in mosses was the sampled species. In 2015, the atmospheric deposition showed a lower predictive power compared to earlier campaigns. The mean precipitation (2013–2015) is a significant factor influencing the content of Cd, Pb and Zn in moss samples. Altitude (Cu, Hg and Ni) and slope (Cd) are the strongest topographical predictors. With regard to 14 vegetation structure measures studied, the distance to adjacent tree stands is the strongest predictor (Cd, Cu, Hg, Zn, N), followed by the tree layer height (Cd, Hg, Pb, N), the leaf area index (Cd, N, Zn), and finally the coverage of the tree layer (Ni, Cd, Hg). For forests, the spatial density in radii 100–300 km predominates as significant predictors for Cu, Hg, Ni and N. For the urban areas, there are element-specific different radii between 25 and 300 km (Cd, Cu, Ni, Pb, N) and for agricultural areas usually radii between 50 and 300 km, in which the respective land use is correlated with the element contents. The population density in the 50 and 100 km radius is a variable with high explanatory power for all elements except Hg and N.ConclusionsFor Europe-wide analyses, the population density and the proportion of different land-use classes up to 300 km around the moss sampling sites are recommended.
Highlights
IntroductionThe aim of the study was a statistical evaluation of the statistical relevance of potentially explanatory variables (atmospheric deposition, meteorology, geology, soil, topography, sampling, vegetation structure, land-use density, population density, potential emission sources) correlated with the content of 12 heavy metals and nitrogen in mosses collected from 400 sites across Germany in 2015
The aim of the study was a statistical evaluation of the statistical relevance of potentially explanatory variables correlated with the content of 12 heavy metals and nitrogen in mosses collected from 400 sites across Germany in 2015
Maximum statistical correlations between precipitation and heavy metals (HM) content in moss samples are found for Ni and for Pb
Summary
The aim of the study was a statistical evaluation of the statistical relevance of potentially explanatory variables (atmospheric deposition, meteorology, geology, soil, topography, sampling, vegetation structure, land-use density, population density, potential emission sources) correlated with the content of 12 heavy metals and nitrogen in mosses collected from 400 sites across Germany in 2015. For As, Cd, Ni, Pb and N, there is good evidence that atmospheric deposition is one of the main factors for the accumulation of substances in mosses [12, 26, 40]. The level of these correlations varies from element to element depending on the reference areas studied, such as participating states or ecological spatial units [41,42,43,44,45,46,47,48]. Results of deposition modelling [37] offer the opportunity to further substantiate the investigation of potential predictors of element accumulation in moss samples
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