Abstract
According to the model of ideal associated solutions, between one and three associates are usually identified in a typical binary metallic solution with negative deviation from Rouault’s law. According to the phase rule, however, the number of simultaneously coexisting associates must not exceed the number of chemical elements present. In other words, there should be no more than two associates. It is assumed that chemical reactions between the associates eliminate the excess. A special function taking this interaction into account is introduced in the system of equations for the model of ideal associated solutions.
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