Core–shell Si/Cu nanocomposites synthesized by self-limiting surface reaction as anodes for lithium ion batteries

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Core–shell Si/Cu nanocomposites were synthesized via a flexible self-limiting surface reaction without extra reductant for the first time. The nano Si was uniformly coated with Cu nanoparticles with a diameter of 5–10[Formula: see text]nm, which can enhance the electronic conductivity of the nanocomposites and buffer the huge volume change during charge/discharge owing to its high ductility. Benefited from the unique structure, the Si/Cu nanocomposites exhibited a good electrochemical performance as anodes for lithium ion batteries, which exhibited a capacity retention of 656[Formula: see text]mAh/g after 50 cycles and a coulombic efficiency of more than 99%.