Abstract
AbstractHerein we reported a method for copper pivalate mediated, directed functionalization of ortho C−H bonds in (2‐methylthio)aniline benzamides. Diaryl disulfides were used for thiolation, while successful phenoxylation was obtained with phenol as the coupling agent. Our report marks a rare example for flexible transformation of benzamide C(sp2)−H bonds into the corresponding unsymmetrical diaryl ethers and thioethers.
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