Abstract

This article has no abstract. Keywords: wolff rearrangement (arndt-eistert reaction); grignard reaction; intramolecular diazo olefin cyclization; allenic alcohols; phloroglucinol; alkenes; vinylsilanes; copper dienolates of α,β-unsaturated acids; β-Ketophosphonates; copper enolates of esters; alkylation of allylic grignard reagents; alkylation of nitroarenes; reaction of grignard reagents with epoxides; copper dienolate of a β,γ-unsaturated acid; exaltolide; optically active allylic alcohols and homoallylic epoxides; indoles; isoquinolines; CI-catalyzed reactions of RLi and RMgX; alkylation of 1-alkynes; cyclopropanation of allyl α-diazoalkanoates; RX RCF3; arylation of active methylene compounds; coupling of alkynes with organoiodides; sulfones; cross-coupling of organostannanes; conjugate additions; arylations; alkynes; 1,2-bis(trifluoromethyl)alkenes; alkynyl ketones; cyclization; desilylallylation; arylations; exchange reactions; allylic displacements; coupling reaction; arylations; substitution and coupling reactions; propargylic amines; rearrangement; baeyer–villiger oxidation; deoxygenation; coupling reactions; amidine synthesis; heterocycles; addition reactions; substitution; coupling reactions; addition; heterocycles; reduction and carboxylation; coupling reaction; (Catecholatoboryl)triethylammonium tetrachloroaluminate; enantioselective halogenation; synthetic chiral ligands; chromium – carbene complexes

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