Tetrabutylammonium fluoride ( TBAF )

Abstract

This article has no abstract. Keywords: preparation; cleavage of silyl ethers; preparation; hydantoins; conjugate addition of thiols; cleavage of phosphate protecting groups; addition of silylacetylenes to carbonyl compounds; aldol condensation; acylation of hydroxyl groups; alkylation of purines and pyrimidines; nitro-aldol reaction; β-amino alcohols; terminal alkenes; alkylation; homoallylic alcohols; isomerization of methyl-substituted allylsilanes; o-xylylenes; α-allenic alcohols; spirocyclization with 2-silyl-1,3-dithianes; nitro-aldol reaction; [4+2]Cycloreversion; erythro-Nitroaldols; β-hydroxy macrolides; michael addition; “anhydrous reagent”; aldol condensation; macrolactonization; α-hydroxy-β-diketone system; silyl anions; cyclopropyl carbanions; nitro-aldol reaction; selenoaldehydes; thioaldehydes; cleavage of vinylsilanes; aromatic fluorodenitration; macrodilactonization; 2-aza-1,3-dienes; desilylation of siloxanes; as base; eliminations; generation of carbanion equivalents; miscellaneous reactions; as base; gem-difluorocyclopropanes; desilylation; cleavage of enol ethers; desilylation; fluorination; coupling reactions; 3,4-dihydroquinazolin-2-ones; cyclization; decomplexation; desilylation; aldol reactions; indole derivatives; reactions of sulfur compounds; coupling reactions; hydrolysis; condensation reactions; group exchange; rearrangement; desilylation; coupling reactions; defunctionalization; α-trifluoromethylalkanoic esters; β-hydroxy-β-allyl carboxylic acids; cyclization; fluoropyridines; dehydroiodination; transsilylation; fragmentation; fluoroarenes; coupling reactions; nitro alcohols; substitution; elimination; alkylation; deprotection; elimination; condensation; palladacycles; cross-coupling reactions; Suzuki coupling; palladium(II) acetate – silver salts; palladium – aminocarbene complexes