Abstract

AbstractA novel and facile synthesis of aryl benzyl sulfones was accomplished for the first time through copper‐catalyzed decarboxylative reductive sulfonylation reaction between α‐oxocarboxylic acids and aryl sulfonyl hydrazines. The protocol proceeds smoothly under simple conditions, and has the advantages of simple operation, high yields and good functional group compatibility. This approach realizes a conceptually novel methodology for aryl benzyl sulfone synthesis under a decarboxylative reductive progress.

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