Abstract
Sets of metal tetrapyrrole complexes are presented in which unusual geometries and/or stoichiometries occur as compared with the usual distorted octahedral structures and molar 1:1 ratio of metal and tetrapyrrole ligand normally found in metal complexes of porphyrins, phthalocyanines or other tetrapyrrole ligands (hydroporphyrins, corroles, etc.).
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