Controlling the Cooling Rate of Hydrothermal Synthesis to Enhance the Supercapacitive Properties of β-Nickel Hydroxide Electrode Materials.

Abstract

The demand for power storage devices with good quality, fast charging and high energy density is becoming more and more urgent in today's electronic technology. For batteries and traditional capacitors, it is an insurmountable challenge to combine fast charging and discharging, large capacitance and long-life properties. The characteristics of supercapacitors can meet all the above requirements at the same time. In this study, a simple one-step hydrothermal method was successfully used to grow β-nickel hydroxide nanocone particles directly on the 3D foamed nickel substrate as a working electrode material for supercapacitors. After growing β-nickel hydroxide crystals on 3D foamed nickel substrate, by controlling the cooling rate, a well-crystalized β-nickel hydroxide with good capacitance characteristics can be obtained. Cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) and electrochemical impedance spectroscopy (EIS) were used to analyze the capacitance characteristics of the β-nickel hydroxide electrode. The research results show that the specific capacitance value of the β-Ni(OH)2/3D nickel foam electrode material prepared at the cooling rate of 10 °C/h can reach 539 F/g with the charge-discharge test at a current density of 3 A/g. After 1000 continuous charge and discharge cycles, the material still retains 94.1% of the specific capacitance value.