Abstract
In this work, monodispersed, well-shaped platinum (3.2 - 6.4 nm), rhodium (2.4 - 5.1 nm), palladium (3.2 - 5.3 nm) nanoparticles capped with poly(vinylpyrrolidone) were synthesized by a polyol reduction method in an ethylene glycol solution at temperature of 190℃. The influences of synthetic parameters on the size and morphology of the noble metal nanoparticles have been systematically investigated. The noble metal nanoparticles were characterized by means of UV-vis, laser scattering particle size distribution analysis (LSPSDA) and transmission electron microscopy (TEM). The experimental results showed that the particle size of metals nanoparticles, the morphology of which was spherical, increased with the raise of metal precursor concentration as well as the amount of PVP. The optimal molar ratio of PVP/metal and metal precursor concentration for the fabrication of Pt, Rh, and Pd nanoparticles with uniform distribution were 10 and 0.1 mM, respectively. The morphologies of the Rh nanoparticles with the size of 5.1 nm were polygons, including hexagons, pentagons, and triangles.
Highlights
Noble metal nanoparticles (NPs) with a narrow size distribution are valuable technological importance because of their unique physi-chemical properties and applications in the fields of catalysis, information storage, optoelectronics, sensors, fine chemicals synthesis, oil refining processes, and fuel cell technology
The noble metal nanoparticles were characterized by means of UV-vis, laser scattering particle size distribution analysis (LSPSDA) and transmission electron microscopy (TEM)
We report a one-step polyol synthesis of monodispersed, well-shaped Pt (3.2 - 6.4 nm), Rh (2.4 5.1 nm), and Pd (3.2 - 5.3 nm) nanoparticles at temperature of 190 ̊C in a polyol system, using ethylene glycol as the reducing solvent and poly(vinylpyrrolidone) as the capping agent
Summary
Noble metal nanoparticles (NPs) with a narrow size distribution are valuable technological importance because of their unique physi-chemical properties and applications in the fields of catalysis, information storage, optoelectronics, sensors, fine chemicals synthesis, oil refining processes, and fuel cell technology. Much attention has been paid in recent years to develop methods of synthesizing monodispersed and size/shape controlled noble metal nanoparticles (Pt [8,9,10], Rh [11,12,13], Pd [14,15], Ir [16], Au [17,18], and Ag [19,20]) by tuning the particle growth kinetics in the processes of fabricating. Xia and co-workers [23] investigated the synthesis and stability of Rh multipods in a polyol system, which showed interesting surface plasmonic properties. Son and co-workers [22] prepared monodispersed oleyl amine-capped Rh tetrahedral nanocrystals, which displayed excellent arenes hydrogenation activities. The size of the Rh nanoparticles is smaller than that reported before
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