Abstract
Phosphine imides with a boryl substituent 3–5 were synthesized. Their structures were revealed to have a tetracoordinated boron and a phosphorus atom, featuring the N–B coordination by X-ray crystallographic analysis and NMR spectroscopy. The phosphine imide moiety was persistent to hydrolysis, methylation, and the aza-Wittig reaction. The N–B coordination remained intact upon treating with pyridine or fluoride ion. © 2012 Wiley Periodicals, Inc. Heteroatom Chem 23:429–434, 2012; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.21033
Full Text
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call