Control of particle growth and enhancement of photoluminescence, adsorption efficiency, and photocatalytic activity for zinc sulfide and cadmium sulfide using CoAl-layered double hydroxide system

Abstract

The fabrication of zinc sulfide (ZnS) and cadmium sulfide (CdS) hybrids was carried out by the sulfidization of Zn(II) or Cd(II) adsorbed in dodecylsulfate modified CoAl-layered double hydroxide through solid-liquid reaction. The TEM images showed the nanocrystals of ZnS (2.61 nm) or CdS (3.29 nm) orderly distributed on the nanosheets. The BET surface area of ZnS (1.13 m2/g) and CdS (0.78 m2/g) was largely improved by intercalating in the interlayer space of CoAl-layered double hydroxide system (15-20 m2/g). The spectroscopic observations further confirmed the formation of ZnS or CdS nanoparticles in the hybrid as the evidence of the blue-shifted absorption onset (39-44 nm), and the increase of the photoluminescence intensity (3-4 times) relative to those of bare ZnS and CdS. The nanohybrids could be applicable as the adsorbent and photocatalyst on purifying wastewater contaminated with Congo red dye. By the adsorptive removal, the hybrids exhibited the maximum adsorption capacity of 216-234 mg/g, resulting from the effect of CoAl-layered double hydroxide. In addition, the photocatalytic degradation was completely conducted by using CdS hybrid with the rate constant of 0.0115 min-1, because the host-guest and/or guest-guest interactions promoted the greater optical performance, and adsorption and photocatalytic efficiencies.