Contribution of Precambrian basements to the Mesozoic ore-fluid system: An illustration using the Majiayao gold deposit, Jiaodong, China

Abstract

In contrast to most Mesozoic granite-hosted gold deposits in the giant Jiaodong gold province (China), the Majiayao deposit represents a significant example hosted in the Archean high-grade metamorphic terrane. The mineralization is characterized by auriferous quartz-sulfide veins together with notable Fe-bearing carbonates (ankerite and siderite), iron oxides and barite. In this study, the comprehensive in-situ analyses of vein-hosted hydrothermal minerals (such as: xenotime U-Pb dating, ankerite Rb-Sr isotopes and monazite Sm-Nd isotopes) and sulfur isotopic analyses of gold-bearing sulfides are used to constrain the timing of mineralization and to better understand the ore genesis. The syn-ore hydrothermal xenotime yielded a U-Pb age of 120.0 ± 1.2 Ma marking timing of gold mineralization, which is much younger than wallrocks’ latest metamorphism at 1950 to 1850 Ma. The relatively higher and variable initial 87Sr/86Sr ratios (0.715809–0.718753) of ore-related ankerite may be leached from ore-hosting Archean metamorphic rocks and/or regional Neoproterozoic Penglai Group low-grade metasedimentary rocks via extensive fluid-rock interactions. This inference is also supported by the newly reported near-zero δ34S values (–1.2 to 1.4‰) of pyrite from altered wallrocks, which are significantly comparable to the surrounding Archean plagioclase amphibolite. The monazite has relatively homogenous εNd(t=120Ma) values ranging from –19.3 to –17.6, which are much higher than the Nd isotope compositions of the ore-hosting Archean high-grade metamorphic rocks. Combining the widespread mafic dykes and previous relevant geochemical studies, it is proposed that the ore-forming fluids were probably derived from deeply mantle-related contents, followed by intense interaction with Archean basements at the shallow crustal level. In addition, the progressive decrease of δ34S values of pyrite and more appearances of iron oxides and barite from early to late mineralization stages, are ascribed to gradual fluid oxidation by extensive carbonatization of Fe-rich Archean wallrocks.